One night, a Star of Life falls down the chimney of a bakery nestled deep in the forest, causing the dough in the oven to come to life. The dough becomes Anpanman, a superhero made of anpan (a sweet roll with bean jam filling). Together with his friends, Anpanman fights his rival Baikinman and helps the malnourished.
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(Source: Anime News Network)

Baikinman is snatched by a black cloud inhabited by a princess who loves black, Kuroyukihime. She is immediately thrilled with him and starts making trouble with him, turning everything black. However, both Dokin-chan and Anpanman are determined to stop her.

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